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Porphyrin Ribbons Reached the Conductance Quantum in Charged Molecular Junctions

A porphyrin nanoribbon study reached the conductance quantum in charged single-molecule junctions, not a practical wire with literal zero resistance.
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Researchers reported that charged porphyrin molecular junctions could reach the conductance quantum, a result described in headlines as transporting charge “with no resistance.” The experiment did not demonstrate a bulk material, everyday wire or practical device with literal zero resistance: it measured electron transmission through individual, custom-made molecular ribbons connected to gold electrodes.

What the researchers measured

In a 2024 Journal of the American Chemical Society study, Jie-Ren Deng and colleagues tested edge-fused porphyrin nanoribbons in single-molecule junctions. The series contained up to eight nickel-porphyrin units; the longest members reached 7.1 nanometres. Trimethylsilyl alkynes at the ends served as proto-anchor groups for making contacts with gold electrodes. The team used scanning tunnelling microscope break-junction (STM-BJ) measurements to characterize conductance. The paper describes these specific molecular-junction experiments, not a ready-to-use wire.

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How conductance changed

Low-bias transport

With low-resistance gold-acetylide contacts, the ribbons reached low-bias conductance as high as 10−2 G0, where G0 is the conductance quantum. Electron transport at low bias remained suppressed compared with an ideal system.

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Charged, high-conductance states

When bias induced charging in the junction, the molecules’ frontier orbitals realigned with the electrodes. In those high-conductance states, the reported conductance reached 1 G0, stated in the paper as 77.5 μS and corresponding to a current of 20 μA. These figures belong to the study’s experimental conditions; they are not specifications for a practical electrical wire.

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Conductance–voltage traces often showed peaks at zero bias. The researchers interpreted those peaks as evidence that a molecular energy level was resonant with the electrode Fermi level. The effect was most pronounced in longer ribbons, which had smaller HOMO–LUMO gaps.

What “no resistance” means here

Conductance reaching 1 G0 is a result about transmission through a molecular junction in a particular charged state. The headline phrase “no resistance” is shorthand for that result, not evidence of a bulk superconductor or a wire with zero resistance in ordinary use. The study does not establish a room-temperature device, a finished product or a material that can carry current without resistance outside the measured junction conditions. The authors’ paper describes the charging-driven orbital realignment and its effect on conductance.

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How this differs from porphyrin-fused graphene nanoribbons

A separate 2024 study, “Porphyrin-fused graphene nanoribbons” in Nature Chemistry, investigated a different material: a hybrid graphene nanoribbon made using solution-phase synthesis. It reported high local charge mobility measured with ultrafast optical-pump terahertz-probe spectroscopy, as well as prototype single-nanoribbon field-effect and single-electron transistor devices. Those mobility and transistor findings are not results of the STM-BJ porphyrin-junction study. The two works differ in structure, measurement and reported outcome.

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