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1Scan for outdated or missing drivers - takes under a minute2Repair Windows errors before they cause bigger problems3Fix the driver behind crashes, sound loss and screen glitchesA 2020 study captured structural changes in supercooled liquid water from 135 to 245 kelvin, finding reversible, reproducible evidence consistent with a temperature-dependent mixture of two liquid structures. The result helps explain why water behaves unusually, but it does not prove that water has a liquid–liquid critical point at atmospheric pressure.
Why is water considered unusual?
Water has a set of physical properties that differ from the patterns expected for many other liquids. Models proposed to explain these anomalies suggest that liquid water may contain two kinds of local structure, with their relative proportions changing with temperature. The study by Loni Kringle and colleagues tested for structural changes consistent with that picture; it did not claim to explain every unusual property of water.
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What did the supercooled-water study measure?
Supercooled water is liquid water cooled below its usual freezing point without crystallizing. It is difficult to study because it can crystallize rapidly in the temperature range of interest. Kringle, Wyatt A. Thornley, Bruce D. Kay, and Greg A. Kimmel used nanosecond laser pulses to heat thin water films briefly, then rapidly cooled them. Infrared spectroscopy tracked the water’s structure during these short-lived states.
The paper, “Reversible structural transformations in supercooled liquid water from 135 to 245 K,” was published in Science in 2020. Its abstract describes measurements across 135–245 K. Read the paper abstract in Science; the Pacific Northwest National Laboratory publication record also summarizes the study.
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What changed as the water cooled?
The infrared measurements showed structural changes consistent with a mixture of two motifs, commonly described as high-temperature-like and low-temperature-like liquid structures. The fraction associated with the high-temperature motif declined rapidly as temperature fell from 245 K to 190 K. This trend is consistent with two-state mixture models, in which the balance between the two structural motifs shifts with temperature.
The authors also reported that the structural changes were reversible and reproducible. Loni Kringle, a postdoctoral researcher and study co-author, said: “A key observation is that all of the structural changes were reversible and reproducible,” PNNL’s announcement of the study explains the result for a general audience.
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Can water exist as two liquids?
The experiment supports a model in which liquid water’s structure reflects a temperature-dependent mixture of two motifs. That is not the same as showing that two distinct liquid phases coexist under ordinary conditions. The paper says the measurements are consistent with two-state mixture models in the supercritical regime.
Nor did the experiment directly measure water density. It therefore does not establish a liquid–liquid critical point at atmospheric pressure. Chemistry World’s article frames the findings as clues to water’s unusual behavior, rather than a final resolution of the question: its coverage of the study discusses that interpretation.
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What the evidence does—and does not—show
- Direct measurement: Infrared spectroscopy tracked structural changes in briefly heated, rapidly cooled thin films of supercooled water.
- Repeatability: The transformations were reported as reversible and reproducible.
- Supported interpretation: The measured changes are consistent with a temperature-dependent mixture of two structural motifs and with two-state mixture models.
- Not established: The study did not demonstrate an atmospheric-pressure liquid–liquid critical point or settle the full explanation for water’s anomalies.
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